Product ID:QCS-TMAA/SPEX-TMAA;QC SAMPLES - TRACE METALS AA - CONC 3
MSDS Date:11/16/1993
FSC:6810
NIIN:00D004795
MSDS Number: BYTGX

SPEX CHEMICAL DIVISION

203 NORCORSS AVE.
METUCHEN, NJ 08840
US

Emergency Phone: 908-549-7144 800-424-9300(CHEMTREC)

Info Phone: 908-549-7144 908-603-9647-FAX

Preparer: VANAJA SWAKUMAN

Cage: EO247

SPEX CHEMICAL DIVISION

METUCHEN, NJ 08840 US

Telephone: 908-494-1663/549-7144

Cage: EO247

NITRIC ACID (SARA 302/313) (CERCLA)

CAS: 7697-37-2

RTECS: QU5775000

Fraction By Weight: 5%

OSHA PEL 2 PPM

ACGIH TLV: 2 PPM/4 STEL; 9495

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

WATER

CAS: 7732-18-5

RTECS: ZC0110000

Fraction By Weight: 90-97%

BARIUM (SARA 313)=500PPM

CAS: 7440-39-3

RTECS: CQ8370000

OSHA PEL 0.5 MG/M3

CALCIUM, METAL=500PPM

CAS: 7440-70-2

RTECS: EV8040000

IRON=200PPM

CAS: 7439-86-6

RTECS: NO6925000

POTASSIUM, METAL=100PPM

CAS: 7440-09-7

RTECS: TS6460000

SODIUM (CERCLA)=100PPM

CAS: 7440-23-5

RTECS: VY0686000

MAGNESIUM=50PPM

CAS: 7439-95-4

RTECS: OM2100000

ZINC (SARA 313) (CERCLA)=50PPM

CAS: 7440-66-6

RTECS: ZG8600000

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

LD50 LC50 Mixture:TLV FOR NITRIC ACID IS 5 MG/M3 TWA
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:**CORROSIVE** EYES:MAY CAUSE
IRRITATION OR BURNS.SKIN:MAY CAUSE IRRITATION OR BURNS.INGEST:MAY
CAUSE GI TRACT IRRITATION OR BURNS.INHAL:MAY CAUSE RESPIRATORY
IRRITATION.
Explanation of Carcinogenicity:THERE ARE NO INGREDIENTS ABOVE 0.1%
WHICH ARE IDENTIFIED AS CARCINOGENS BY NTP,IARC OR OSHA.
Effects of Overexposure:SKIN:NITRIC ACID LEAVES A YELLOW TO BROWN STAIN
ON SKIN.INHAL:SPASM,INFLAMMATION AND SWELLING OR THE THROAT AND
LUNG(BURNING,COUGHING,WHEEZING,LARYNGITIS,SHORTNESS OF
BREATH,HEADACHE,NAUSEA,VOMITING). PROLONGED EXPOSURE ERODES
TEETH.INGEST:MOUTH,ESOPHAGEAL AND GI TRACT PAIN.
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING
RESPIRATORY AILMENTS MAY BE AT INCREASED RISK FROM EXPOSURE.

First Aid:SKIN:REMOVE CONTAMINATED CLOTHING;WASH WITH WATER.EYES:FLUSH
WITH WATER FOR 15 MINUTES.INHAL:REMOVE TO FRESH AIR.GIVE OXYGEN OR
ARTIFICIAL RESPIRATION IF NEEDED.INGEST:DO NOT INDUCE VOMITING.GET
PROMP T QUALIFIED MEDICAL ATTENTION.IF CONSCIOUS,ADMINISTER LARGE
AMOUNTS OF WATER OR MILK.**IF IRRITATION PERSISTS,GET MEDICAL
ATTENTION**

Flash Point:NONE
Extinguishing Media:USE MEDIA APPROPRIATE FOR SURROUNDING FIRE.
Fire Fighting Procedures:USE A SELF-CONTAINED BREATHING APPARATUS AND
FULL PROTECTIVE EQUIPMENT.
Unusual Fire/Explosion Hazard:**OXIDIZER** NITRIC ACID REACTS WITH
METALS TO FORM EXPLOSIVE H*2(GAS).FIRE CONDITIONS MAY EVOLVE TOXIC
FUMES.

Spill Release Procedures:VENTILATE AREA.USE PROPER PERSONAL AND
RESPIRATORY PROTECTION.NEUTRALIZE WITH SODA ASH OR LIMESTONE;SOAK
UP WITH NON-COMBUSTIBLE INERT ADSORBANT(EG.CLAY);PLACE COLLECTED
MATERIAL IN AN APPROPRIATE CON TAINER FOR DISPOSAL;CLEAN SPILL
AREA.
Neutralizing Agent:SODA ASH OR LIMESTONE.

Handling and Storage Precautions:STORE IN A COOL,DRY,WELL-VENTILATED
PLACE.KEEP CONTAINER CLOSED WHEN NOT IN USE.KEEP AWAY FROM
HEAT,SPARKS,FLAMES AND INCOMPATIBLE MATERIALS.
Other Precautions:CONCENTRATED NITRIC ACID WILL ATTACK SOME FORMS OF
PLASTICS,RUBBERS OR COATINGS.

Respiratory Protection:WHERE ENVIRONMENTAL CONTROLS ARE LACKING OR IN
ENCLOSED SPACES USE EITHER A SELF-CONTAINED BREATHING APPARATUS OR
A NIOSH/MSHA APPROVED RESPIRATOR FOR ACID GAS,DEPENDING ON THE
AIRBORN CONCENTRATION.
Ventilation:LOCAL VENTILATION AT THE WORKSITE;MECHANICAL(GENERAL)
VENTILATION TO MAINTAIN TLV/PEL.
Protective Gloves:ACID RESISTANT
Eye Protection:CHEMICAL SPLASH GOGGLES
Other Protective Equipment:PROTECTIVE CLOTHING,AS NEEDED.PROVIDE A
LOCAL EYE WASH STATION AND SAFETY SHOWER.
Work Hygienic Practices:EXECISE GOOD LABORATORY PRACTICES.WASH HANDS
AFTER USE AND BEFORE EATING.
Supplemental Safety and Health
**IRRITANT - OXIDIZER - CORROSIVE**

HCC:C1
Spec Gravity: 1
pH:ACID
Solubility in Water:COMPLETE
Appearance and Odor:LIQUID;TRANSPARENT;ACRID ODOR.
Corrosion Rate:CORROSIV

Stability Indicator/Materials to Avoid:YES
STRONG BASES(WILL CAUSE VIOLENT SPATTERING).CONTACT WITH REDUCING
AGENTS OR COMBUSTIBLES MAY CAUSE IGNITION.
Stability Condition to Avoid:COMBUSTIBLE ORGANIC OR READILY OXIDIZABLE
MATERIALS(EG.WOOD,ALCOHOL,TURPENTINE,METAL POWDERS,H*2S).
Hazardous Decomposition Products:OXIDES OF NITROGEN.

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL,STATE AND
LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.